全文获取类型
收费全文 | 46135篇 |
免费 | 2273篇 |
国内免费 | 1369篇 |
专业分类
化学 | 25256篇 |
晶体学 | 609篇 |
力学 | 2238篇 |
综合类 | 79篇 |
数学 | 4621篇 |
物理学 | 16974篇 |
出版年
2023年 | 332篇 |
2022年 | 484篇 |
2021年 | 681篇 |
2020年 | 786篇 |
2019年 | 726篇 |
2018年 | 847篇 |
2017年 | 729篇 |
2016年 | 1185篇 |
2015年 | 827篇 |
2014年 | 1223篇 |
2013年 | 2322篇 |
2012年 | 2414篇 |
2011年 | 2790篇 |
2010年 | 1954篇 |
2009年 | 1949篇 |
2008年 | 2216篇 |
2007年 | 2107篇 |
2006年 | 1919篇 |
2005年 | 1659篇 |
2004年 | 1482篇 |
2003年 | 1300篇 |
2002年 | 1200篇 |
2001年 | 1543篇 |
2000年 | 1175篇 |
1999年 | 1049篇 |
1998年 | 813篇 |
1997年 | 746篇 |
1996年 | 668篇 |
1995年 | 632篇 |
1994年 | 572篇 |
1993年 | 500篇 |
1992年 | 553篇 |
1991年 | 532篇 |
1990年 | 527篇 |
1989年 | 464篇 |
1988年 | 480篇 |
1987年 | 462篇 |
1986年 | 396篇 |
1985年 | 457篇 |
1984年 | 474篇 |
1983年 | 346篇 |
1982年 | 394篇 |
1981年 | 379篇 |
1979年 | 396篇 |
1978年 | 375篇 |
1977年 | 392篇 |
1976年 | 390篇 |
1975年 | 339篇 |
1974年 | 317篇 |
1973年 | 333篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
João Marcos G. Barbosa Milenna K. Fernandes Rodrigues Lurian C. David Taynara C. e Silva Danielly A. Fortuna Lima Naiara Z. Pereira Emmanuel B. D'Alessandro Anselmo E. de Oliveira Paulo H. Jorge da Cunha Maria Clorinda S. Fioravanti Nelson R. Antoniosi Filho 《Biomedical chromatography : BMC》2020,34(11):e4935
An innovative volatolomic approach employs the detection of biomarkers present in cerumen (earwax) to identify cattle intoxication by Stryphnodendron rotundifolium Mart., Fabaceae (popularly known as barbatimão). S. rotundifolium is a poisonous plant with the toxic compound undefined and widely distributed throughout the Brazilian territory. Cerumen samples from cattle of two local Brazilian breeds (‘Curraleiro Pé-Duro’ and ‘Pantaneiro’) were collected during an experimental intoxication protocol and analyzed using headspace (HS)/GC–MS followed by multivariate analysis (genetic algorithm for a partial least squares, cluster analysis, and classification and regression trees). A total of 106 volatile organic metabolites were identified in the cerumen samples of bovines. The intoxication by S. rotundifolium influenced the cerumen volatolomic profile of the bovines throughout the intoxication protocol. In this way, it was possible to detect biomarkers for cattle intoxication. Among the biomarkers, 2-octyldecanol and 9-tetradecen-1-ol were able to discriminate all samples between intoxicated and nonintoxicated bovines. The cattle intoxication diagnosis by S. rotundifolium was accomplished by applying the cerumen analysis using HS/GC–MS, in an easy, accurate, and noninvasive way. Thus, the proposed bioanalytical chromatography protocol is a useful tool in veterinary applications to determine this kind of intoxication. 相似文献
22.
We propose a system of time-division multiplexing(TDM) and spatial frequency-division multiplexing(SFDM). Extrinsic Fabry–Perot interferometric sensors are applied to detect weak acoustic signals. The broadband source is employed, the light from it is modulated by a pulse signal sequence and is efficiently amplified by semiconductor optical amplifiers. Experimental results show that the equivalent noise pressure spectrum level is-97.2 d B re 1 rad/√Hz below 1250 Hz, and the cross talk between two sensors in one TDM channel is-32.7 d B with a cavity length difference of 60 μm. The number of sensors in this multiplexing system can theoretically reach 160. 相似文献
23.
We proposed an electro-optic modulator with two-bus one-ring (TBOR) structure to improve the extinction ratio and reduce insert loss. It has a dual output compared with one-bus one-ring structure. In addition, double-layer graphene makes it possible for the modulation in the visible to mid-infrared wavelength range. It shows that this new electro-optic modulator can present two switching states well with low insertion loss, high absorption and high extinction ratio. At , when the switching states are based on the chemical potential, and , the insertion losses of both output ports are less than 2 dB, the absorption of the output port coupled via a micro-ring reaches 45 dB and the extinction ratio reaches 14 dB. When the refractive index of the dielectric material is 4.2, the applied voltage will be less than 1.2 V, thus can be used in low-voltage CMOS technology. 相似文献
24.
25.
In this Letter,a novel system for adaptively correcting the phase of a dynamic multimode beam is proposed.While using merely one spatial light modulator,the phase measurement of the first-order diffraction pattern and the correction of the zeroth diffraction order are simultaneously realized.The real-time experimental result is obtained at a control rate of 10 Hz.The power-in-the-bucket value is improved from 38.5%to 61.8%,even with fundamental mode content that is consistently below 30%.To the best of our knowledge,this is the first implementation of real-time adaptive correction of the entire multimode beam. 相似文献
26.
Valiullina Z. R. Galeeva A. M. Miftakhov M. S. 《Russian Journal of Organic Chemistry》2021,57(9):1461-1465
Russian Journal of Organic Chemistry - The Reformatsky reaction of (3R,4R)-4-acetoxy-3-((1R)-1-{[tert-butyl(dimethyl)silyl]oxy}ethyl)azetidin-2-one with ethyl 4-bromo-3-oxopentanoate gave... 相似文献
27.
28.
Zhang Kailun Wu Hongjuan Wang Tian Yao Meng Xie Jixing Jiao Yunhong 《Journal of Thermal Analysis and Calorimetry》2021,145(6):3067-3075
Journal of Thermal Analysis and Calorimetry - A phosphazene-based flame retardant (PBFA) was synthesized by hexachlorocyclotriphosphazene and N-aminoethylpiperazine. To improve the flame retardancy... 相似文献
29.
Turyanskiy A. G. Vorob’ev N. S. Gizha S. S. Makushina V. A. Mikhal’kov Yu. M. Smirnov A. V. Pirshin I. V. Senkov V. M. Shashkov E. V. Fishman R. I. Ziyatdinova M. Z. Komel’kov A. S. 《JETP Letters》2020,112(11):734-738
JETP Letters - The possibility of stable generation of intense characteristic Cs radiation upon electronic excitation of a Mo anode target heat treated in Cs and O2 vapors is demonstrated. The... 相似文献
30.
Susana Estopiñá-Durán Liam J. Donnelly Euan B. Mclean Bryony M. Hockin Prof. Alexandra M. Z. Slawin Dr. James E. Taylor 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(15):3950-3956
A combination of pentafluorophenylboronic acid and oxalic acid catalyses the dehydrative substitution of benzylic alcohols with a second alcohol to form new C−O bonds. This method has been applied to the intermolecular substitution of benzylic alcohols to form symmetrical ethers, intramolecular cyclisations of diols to form aryl-substituted tetrahydrofuran and tetrahydropyran derivatives, and intermolecular crossed-etherification reactions between two different alcohols. Mechanistic control experiments have identified a potential catalytic intermediate formed between the aryl boronic acid and oxalic acid. 相似文献